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Calcium carbonate (limestone) is heated to form calcium oxide (quicklime) and carbon dioxide: It is an endothermic reaction and the equilibrium lies far to the left at low temperatures. Only at about 1200 K does the partial pressure of carbon dioxide exceed atmospheric pressure and the decomposition proceeds to completion.
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Limestone stalactites. The most common stalactites are speleothems, which occur in limestone caves. They form through deposition of calcium carbonate and other minerals, which is precipitated from mineralized water is the chief form of calcium carbonate rock which is dissolved by water that contains carbon dioxide, forming a calcium bicarbonate solution in caverns.
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Speleogenesis is the origin and development of caves, the primary process that determines essential features of the hydrogeology of karst and guides its evolution. It often deals with the development of caves through limestone, caused by the presence of water with carbon dioxide dissolved within it, producing carbonic acid which permits the dissociation of the calcium carbonate in the limestone.
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